Main-Chain Cationic Polyelectrolytes: Design, Synthesis, and Applications

Polyelectrolytes have attracted a lot of attention spanning across disciplines, including polymer chemistry, materials chemistry, chemical biology, chemical engineering, as well as device physics, as a result of their widespread applications in sensing, biomedicine, food industry, wastewater treatment, optoelectronic devices, and renewable energy. In this review, we focus on the crucial synthetic strategies of structurally different classes of main-chain cationic polyelectrolytes. As a result of the presence of charged moieties in the main polymeric backbone, their solubility and photophysical properties can be easily tuned. Main-chain cationic polyelectrolytes provide various unique characteristics, including solubility in aqueous and organic solvents, easy processability, ease of film formation, ionic interaction, main-chain-directed charge transport, high conductivity, and aggregation. These properties make the main-chain polyelectrolyte a potential candidate for numerous applications ranging from chemo- and biosensing, antibacterial activity, optoelectronics, electrocatalysis, water splitting, ion conduction, to dye-sensitized solar cells.