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Related Concept Videos

Energy Diagrams, Transition States, and Intermediates02:13

Energy Diagrams, Transition States, and Intermediates

Free-energy diagrams, or reaction coordinate diagrams, are graphs showing the energy changes that occur during a chemical reaction. The reaction coordinate represented on the horizontal axis shows how far the reaction has progressed structurally. Positions along the x-axis close to the reactants have structures resembling the reactants, while positions close to the products resemble the products.  Peaks on the energy diagram represent stable structures with measurable lifetimes, while other...
Thermal and Photochemical Electrocyclic Reactions: Overview01:26

Thermal and Photochemical Electrocyclic Reactions: Overview

Electrocyclic reactions are reversible reactions. They involve an intramolecular cyclization or ring-opening of a conjugated polyene. Shown below are two examples of electrocyclic reactions. In the first reaction, the formation of the cyclic product is favored. In contrast, in the second reaction, ring-opening is favored due to the high ring strain associated with cyclobutene formation.
Thermal Sigmatropic Reactions: Overview01:16

Thermal Sigmatropic Reactions: Overview

Sigmatropic rearrangements are a class of pericyclic reactions in which a σ bond migrates from one part of a π system to another. These are intramolecular rearrangements where the total number of σ and π bonds remain unchanged.
Sigmatropic shifts are classified based on an order term [i, j ], where i and j indicate the number of atoms across which each end of the σ bond migrates. Below are examples of a [3,3] sigmatropic shift in 1,5-hexadiene, referred to as...
Radical Reactivity: Nucleophilic Radicals01:16

Radical Reactivity: Nucleophilic Radicals

Radicals adjacent to electron-donating groups are called nucleophilic radicals. These radicals readily react with electrophilic alkenes. The SOMO–LUMO interactions are the driving force for the reaction, where the high-energy SOMO of the electron-rich, nucleophilic radicals interacts with the low-energy LUMO of the electron-deficient, electrophilic alkenes. Such SOMO–LUMO interactions are the basis of reactive radical traps, affecting the selectivity in radical reactions. For instance, consider...
Thermal Stress01:09

Thermal Stress

If the temperature of an object is changed while it is prevented from expanding or contracting, the object is subjected to stress. The stress is compressive if the object expands in the absence of constraint and tensile if it contracts. This stress resulting from temperature change is known as thermal stress. It can be quite large and can cause damage. To avoid this stress, engineers may design components so they can expand and contract freely. For instance, on highways, gaps are deliberately...
Thermal expansion and Thermal stress: Problem Solving01:27

Thermal expansion and Thermal stress: Problem Solving

San Francisco's Golden Gate Bridge is exposed to temperatures ranging from -15 °C to 40 °C. At its coldest, the main span of the bridge is 1275 m long. Assuming that the bridge is made entirely of steel, what is the change in its length between these temperatures?
To solve the problem, first, identify the known and unknown quantities. The initial length (L) of the bridge is 1275 m, the coefficient of linear expansion (α) for steel is 12 x 10-6/°C, and the change in temperature (ΔT) is 55 °C.

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Active search for a reactive target in thermal environments.

Byeong Guk Go1, Euijin Jeon2, Yong Woon Kim1

  • 1Department of Physics, Korea Advanced Institute of Science and Technology, Daejeon 34141, Korea.

The Journal of Chemical Physics
|January 23, 2024
PubMed
Summary

An active particle

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Area of Science:

  • Statistical physics
  • Active matter physics
  • Biophysics

Background:

  • Active particles exhibit complex behaviors in thermal environments.
  • Understanding search strategies is crucial in various physical and biological systems.
  • Run-and-tumble particles are a common model for active matter.

Purpose of the Study:

  • To analytically determine the mean searching time (MST) for a run-and-tumble particle.
  • To identify optimal self-propulsion velocities that minimize MST.
  • To investigate the influence of diffusion and target absorption strength on search efficiency.

Main Methods:

  • Solving the Fokker-Planck equation for a uniform initial distribution.
  • Analytical calculation of mean searching time.
  • Application of the Landau approach to analyze phase transitions.

Main Results:

  • An optimal self-propulsion velocity exists that minimizes MST.
  • High diffusion constants favor purely diffusive Brownian motion over active motion.
  • Phase diagrams reveal distinct passive-efficient and active-efficient regions.
  • Transition of optimal velocity can be continuous or discontinuous based on absorption strength.

Conclusions:

  • The study provides a comprehensive analysis of active particle search strategies.
  • Optimal search dynamics depend on particle activity, diffusion, and target properties.
  • The findings offer insights into efficient search mechanisms in complex environments.