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Updated: Jun 25, 2026

Synthesis of Platinum-nickel Nanowires and Optimization for Oxygen Reduction Performance
Published on: April 27, 2018
Three-dimensional ordered macroporous design of heterogeneous cobalt-iron phosphides as oxygen evolution
Songan Zhao1, Weijin Cao1, Lu Lu1
1Hebei Provincial Key Laboratory of Green Chemical Technology and High Efficient Energy Saving, Tianjin Key Laboratory of Chemical Process Safety, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin, 300130, People's Republic of China.
None:
Oxygen evolution reaction (OER) plays a key role in electrochemical conversion, which needs efficient and economical electrocatalyst to boost its kinetics for large-scale application. Herein, a bimetallic CoP/FeP2heterostructure with a three-dimensional ordered macroporous structure (3DOM-CoP/FeP2) was synthesized as an OER catalyst to demonstrate a heterogeneous engineering induction strategy. By adjusting the electron distribution and producing a lot of active sites, the heterogeneous interface enhances catalytic performance. High specific surface area is provided by the 3DOM structure. Additionally, at the solid-gas-electrolyte threephase interface, the electrocatalytic reaction exhibits good mass transfer.In situRaman spectroscopy characterization revealed that FeOOH and CoOOH reconstructed from CoP/FeP2were the true OER active sites. Consequently, the 3DOM-CoP/FeP2demonstrates superior OER activity with a low overpotentials of 300/420 mV at 10/100 mA cm-2and meritorious OER durability. It also reveals promising performance as the overall water splitting anode.
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