An entropy trap model of thermodynamic anomalies for dual-amorphous water undergoing liquid-liquid phase transition

Water displays numerous anomalously thermodynamic behaviors. However, the working principles behind these anomalies are not well understood, and the liquid-liquid phase transition (LLPT) is often regarded as the potential reason. In this study, we developed an entropy trap model to characterize the thermodynamic LLPT in dual-amorphous water, i.e. having both low-density and high-density liquid water. From the Adam-Gibbs model and free-volume theory, thermodynamic behaviors of water have been described using the proposed model, in which the constitutive relationships among density, heat capacity, thermal expansivity and glass transition temperature have been formulated. Moreover, the glass transition and its connection to thermodynamic behaviors were also investigated for dual-amorphous water. Finally, experimental data reported in the literature were used to verify effectiveness of the proposed model. This study is expected to provide a physical insight into the anomalous thermodynamics of dual-amorphous water undergoing the LLPT.