Municipal sludge biochar skeletal sodium alginate beads for phosphate removal

A novel Fe/La decorative biochar filled in sodium alginate beads (SA-KBC-Fe/La) was prepared by a simple sol-gel method and applied to adsorb phosphate (P) efficiently from water in this study. The morphology, structure and chemical component of the hydrogel beads were characterized in detail. And the synthesized bead exhibited easy separation and high P uptake of 46.65 mg/g when the Fe: La was of 1: 2 at 298 K with initial P of 100 mg/L, which was much higher than SA gel bead. The adsorption showed that the optimal pH was 6, and the adsorption was met with pseudo-second-order kinetics and Langmuir isothermal models, indicating a chemical adsorption process. The adsorption capacity remained 82 % after 5 cycles of adsorption. The adsorption mechanism of P was mainly of ligand exchange and electrostatic attraction. Compared with other reported adsorbents, the modification of Fe/La could enhance the mechanical property of SA-KBC-Fe/La beads with increasing active sites. Additionally, the involved biochar could lead to excellent thermal stability and hierarchical porous structure of beads with larger specific surface area (54.22 m²/g). The study could provide new ideas for P removal and strategy for the final disposal of municipal sludge.