Chitosan nanofiber paper used as separator for high performance and sustainable lithium-ion batteries

Separators are indispensable components in lithium-ion batteries (LIBs), providing efficient pathways for lithium ions to travel and isolating the positive and negative electrodes to avoid short circuits. However, traditional polyolefin-based separators exhibit inferior electrolyte affinities, limited porosities, and low thermal stabilities. In this study, a novel method was developed to prepare chitosan micro/nanofiber membranes as LIB separators using natural materials. The pore sizes of the chitosan micro/nanofibers separators were modulated by changing the diameters of the chitosan fibers. The results demonstrated that the chitosan nanofiber separators (CSNFs) had superior electrolyte uptake (281 %), excellent thermal dimensional stability, and electrochemical performance in LiFePO₄/Li half-cell, as indicated by the higher discharge capacity after 100 cycles, and higher rate capacity than commercial Celgard2325 separator. This study paves the way for the fabrication of eco-efficient and environment-friendly separators for high-performance LIBs.