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Two-way Valorization of Blast Furnace Slag: Synthesis of Precipitated Calcium Carbonate and Zeolitic Heavy Metal Adsorbent
Published on: February 21, 2017
Sustainable binary/ternary blended mortars with recycled water treatment sludge using fly ash or blast slag:
1Department of Civil Engineering, Faculty of Engineering and Natural Sciences, Malatya Turgut Ozal University, Malatya, Türkiye. ceren.kina@ozal.edu.tr.
Abstract:
Water treatment sludge (WTS) is produced daily and disposed of as hazardous material. It would be advisable to use locally available waste products as supplementary cementitious materials that ensure to be disposed of without harming the environment. As a novelty, this research investigated the potential of using recycled WTS with fly ash (FA) and ground-granulated blast furnace slag (BFS) as ternary blended binders. Thus, it can provide an economical solution and alleviate the adverse environmental effects of excessive production of wastes and cement production. Within this scope, the mortars with 0-30 wt% replacement of cement with modified WTS (MWTS) were produced as binary blend, and also, they were combined with FA/BFS as ternary blended binders. Therefore, optimum utilization of waste products into the mortar in terms of rheological, mechanical, durability, microstructural properties, and environmental-economical aspects was examined. Adding 10% recycled WTS as binary caused higher strengths with lower porosity measured by the mercury intrusion porosimeter test and denser microstructure, as revealed by XRD patterns and SEM results. However, the drawbacks of using recycled WTS, in terms of rheological parameters and environmental-economical aspects, were suppressed by adding FA/BFS with comparable strength values. Specifically, cost, CO2 footprint, and embodied energy were reduced by combining 10% MWTS with FA by 8.87%, 37.88%, and 33.07%, respectively, while 90-day compressive and flexural strength were 5.1% and 5.32% lower. This study developed a feasible solution to use recycled MWTS by obtaining more eco-friendly and cost-effective cement-based materials.
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