Steerable mass transport in a photoresponsive system for advanced anticounterfeiting

Numerous anticounterfeiting platforms using photoresponsive materials have been designed to improve information security, enabling applications in anticounterfeiting technology. However, fabricating sophisticated micro/nanostructures using bidirectional mass transport to achieve advanced anticounterfeiting remains challenging. Here, we propose one strategy to achieve steerable mass transport in a photoresponsive system with the assistance of solvent vapor at room temperature. Upon optimizing the host-guest ratio and the width of photoisomerized areas, wettability gradient is acquired just photo-patterning once, then bidirectional mass transport is realized due to the competition of mass transport induced by surface energy gradient of the material itself and flow of the solvent on the film surface with wettability gradient. Taking advantage of the interaction between solvent and film surface with wettability gradient, this bidirectional polymer flow has been successfully applied in multi-mode anticounterfeiting. This work paves a promising avenue toward high-level information storage in soft materials, demonstrating the potential applications in anticounterfeiting.