Sources and environmental impacts of volatile organic components in a street canyon: Implication for vehicle emission

Street canyons serve as a representative environment that directly reflects the impact of vehicular emissions. Volatile organic compounds (VOCs) sampling during an O₃ pollution event and a PM_2.5 pollution episode was conducted at an urban site and a street canyon in Zhengzhou, China. It has been determined that street canyons suffer from more severe particle and NO_x pollution than the urban site. Additionally, O₃ has been identified as a significant or emerging pollutant in street canyon environments. In terms of VOCs, the street canyon exhibits 1.4 and 1.1 times higher total VOC concentrations compared to the urban site during the O₃ and PM_2.5 pollution episodes, respectively. In the street canyon location, there was a slight increase in the proportion of alkanes and aromatics, while the proportions of oxygenated VOCs and halogenated hydrocarbons decreased. Source apportionment analysis reveals that street canyons were more susceptible to the accumulation of VOCs from coating solvent, liquid petroleum gas (LPG), and gasoline additives. Consequently, the environmental impacts of VOCs originating from coating solvent and LPG were more pronounced in the street canyon location compared to the urban site. The trends of NO_x concentration indicate that future continuously stricter vehicle emission standards and control policies can further reduce vehicle exhaust emissions and more attention needs to be focused on the reduction of non-exhaust emissions (i.e., coating solvent) and LPG vehicles.