Related Experiment Video

Updated: Jul 4, 2025

High Resolution Phonon-assisted Quasi-resonance Fluorescence Spectroscopy
10:40

High Resolution Phonon-assisted Quasi-resonance Fluorescence Spectroscopy

Published on: June 28, 2016

7.5K

Spectral splitting in phase mismatched harmonics

Raz Halifa Levi, Ori Ildis, Assaf Levanon

    Optics Express
    |February 1, 2024
    PubMed
    Summary

    Spectral splitting of high harmonic radiation occurs with chirped laser pulses. This phenomenon, driven by evolving phase-matching conditions, is observed using multi-terawatt laser systems.

    More Related Videos

    Measurement of Scattering Nonlinearities from a Single Plasmonic Nanoparticle15:06

    Measurement of Scattering Nonlinearities from a Single Plasmonic Nanoparticle

    Published on: January 3, 2016

    12.9K
    Measurement of Quantum Interference in a Silicon Ring Resonator Photon Source12:19

    Measurement of Quantum Interference in a Silicon Ring Resonator Photon Source

    Published on: April 4, 2017

    8.4K

    Related Concept Videos

    IR Spectrum Peak Splitting: Symmetric vs Asymmetric Vibrations01:08

    IR Spectrum Peak Splitting: Symmetric vs Asymmetric Vibrations

    Identical bonds within a polyatomic group can stretch symmetrically (in-phase) or asymmetrically (out-of-phase). Similar to hydrogen bonding, these vibrations also influence the shape of the IR peak. Generally, asymmetric stretching frequencies are higher than symmetric stretching frequencies. For example, primary amines exhibit two distinct IR peaks between 3300–3500 cm−1 corresponding to the symmetric and asymmetric N-H stretching, while secondary amines exhibit a single...
    1.0K
    ¹H NMR: Complex Splitting01:13

    ¹H NMR: Complex Splitting

    A proton M that is coupled to a proton X results in doublet signals for M. However, NMR-active nuclei can be simultaneously coupled to more than one nonequivalent nucleus. When M is coupled to a second proton A, such as in styrene oxide, each peak in the doublet is split into another doublet.
    Splitting diagrams or splitting tree diagrams are routinely used to depict such complex couplings. While drawing splitting diagrams, the splitting with the larger coupling constant is usually applied...
    1.3K
    Interpreting ¹H NMR Signal Splitting: The (n + 1) Rule01:10

    Interpreting ¹H NMR Signal Splitting: The (n + 1) Rule

    In the AX proton spin system, proton A can sense the two spin states of a coupled proton X, resulting in a doublet NMR signal with two peaks of equal (1:1) intensity. When proton A is coupled to two equivalent protons (AX2 spin system), the spin states of each X can be aligned with or against the external field, creating three possible scenarios. This results in a 1:2:1  triplet signal, where the central peak corresponds to the chemical shift of A and is twice as large or intense as the...
    1.3K
    ¹H NMR Signal Multiplicity: Splitting Patterns01:13

    ¹H NMR Signal Multiplicity: Splitting Patterns

    When protons A and X are coupled, their nuclear spin energy levels are slightly modified. This is because the energy required to excite proton A to a spin state parallel to proton X is slightly different from the energy required for it to become anti-parallel to spin X. Consequently, there are two possible excitation frequencies for A (A1 and A2), depending on the spin state of X, and vice versa. The mutual nature of coupling implies that the difference between frequencies A1 and A2, indicated...
    5.2K
    ¹³C NMR: ¹H–¹³C Decoupling01:04

    ¹³C NMR: ¹H–¹³C Decoupling

    The probability of having two carbon-13 atoms next to each other is negligible because of the low natural abundance of carbon-13. Consequently, peak splitting due to carbon-carbon spin-spin coupling is not observed in spectra. However, protons up to three sigma bonds away split the carbon signal according to the n+1 rule, resulting in complicated spectra.
    A broadband decoupling technique is used to simplify these complex, sometimes overlapping, signals. Broadband decoupling relies on a...
    1.1K
    ¹H NMR: Interpreting Distorted and Overlapping Signals01:02

    ¹H NMR: Interpreting Distorted and Overlapping Signals

    Spin systems where the difference in chemical shifts of the coupled nuclei is greater than ten times J are called first-order spin systems. These nuclei are weakly coupled, and their chemical shifts and coupling constant can generally be estimated from the well-separated signals in the spectrum.
    As Δν decreases and the signals move closer, the doublets appear increasingly distorted. The intensities of the inner lines increase at the cost of those of the outer lines as the signals are...
    1.0K