Interconversion between multicomponent slider-on-deck and palladium capsule: regulation of catalysis and encapsulation
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Published on: February 2, 2024
Isa Valiyev1, Indrajit Paul1, Yi-Fan Li1
1Center of Micro and Nanochemistry and (Bio)Technology, Organische Chemie I, School of Science and Engineering, Universität Siegen, Adolf-Reichwein-Str. 2, D-57068 Siegen, Germany. schmittel@chemie.uni-siegen.de.
Abstract:
When the slider-on-deck [Cu3(1)(2)]3+ and guest G were treated with palladium(II) ions, the biped 2 was released from [Cu3(1)(2)]3+ generating the nanocage [Pd2(2)4(G)]4+ with guest G being encapsulated (NetState-II). This transformation that was reversed by the addition of DMAP enabled modulation of both the overall fluorescence and the activity of copper(I) catalyzing an aza Hopf cyclization.
