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Updated: Jul 4, 2025

Hydrogen Production and Utilization in a Membrane Reactor
Published on: March 10, 2023
Why efficient bifunctional hydrogen electrocatalysis requires a change in the reaction mechanism
Samad Razzaq1, Kai S Exner1,2,3
1University Duisburg-Essen, Faculty of Chemistry, Theoretical Inorganic Chemistry, Universitätsstraße 5, 45141 Essen, Germany.
Abstract:
Hydrogen evolution reaction (HER) and hydrogen oxidation reaction (HOR) are both two-electron processes that culminate in the formation or consumption of gaseous hydrogen in an electrolyzer or a fuel cell, respectively. Unitized regenerative proton exchange membrane fuel cells merge these two functionalities into one device, allowing to switch between the two modes of operation. This prompts the quest for efficient bifunctional electrode materials catalyzing the HER and HOR with reasonable reaction rates at low overpotentials. In the present study using a data-driven framework, we identify a general criterion for efficient bifunctional performance in the hydrogen electrocatalysis, which refers to a change in the reaction mechanism when switching from cathodic to anodic working conditions. The obtained insight can be used in future studies based on density functional theory to pave the design of efficient HER and HOR catalysts by a dedicated consideration of the kinetics in the analysis of reaction mechanisms.
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