Voltage activation induced MoO₄^2- dissolution to enhance performance of iron doped nickel molybdate for oxygen...

Transition metal-based precatalysts are typically voltage-activated before electrochemical testing in the condition of alkaline oxygen evolution reaction. Nevertheless, the impact of voltage on the catalyst and the anion dissolution is frequently disregarded. In this study, Fe-doped NiMoO₄ (Fe-NiMoO₄) was synthesized as a precursor through a straightforward hydrothermal method, and MoFe-modified Ni (oxygen) hydroxide (MoFe-NiO_xH_y) was obtained via cyclic voltammetry (CV) activation. The effects of voltage on Fe-NiMoO₄ and the dissolved inactive MoO₄^2- ions in the process were examined in relation to OER performance. It has demonstrated that the crystallinity of the catalyst is reduced by voltage, thereby enhancing its electrocatalytic activity. The electron distribution state can be adjusted during the application of voltage, leading to the generation of additional active sites and an acceleration in the reaction rate. Additionally, MoO₄^2- exhibits potential dependence during its dissolution. In the OER process, the dissolution of MoO₄^2- enhances the reconstruction degree of Fe-NiMoO₄ into the active substance and expedites the formation of active Ni(Fe)OOH. Hence, the optimized MoFe-NiO_xH_y exhibited exceptional electrocatalytic performance, with a current density of 100 mA cm^-2 achieved at an overpotential of only 256 mV. This discovery contributes to a more comprehensive understanding of alkaline OER performance under the influence of applied voltage and the presence of inactive oxygen ions, offering a promising avenue for the development of efficient electrocatalysts.