3D Lightweight Interconnected Melamine Foam Modified with Hollow CoFe₂O₄/MXene toward Efficient Microwave Absorption

Considering the increasing severity of electromagnetic wave pollution, the development of high-performance low-filler-content microwave absorbers possessing wide frequency bands and strong absorption for practical applications is a demanding research hotspot. In this study, from the perspectives of the electromagnetic component coordination and structural design, a three-dimensional (3D) interconnected CoFe₂O₄/MXene-melamine foam (MF) was constructed via simple impregnation and a single freeze-drying step. By changing the absorber (CoFe₂O₄/MXene) concentration, the pore opening and electromagnetic properties of the 3D foams can be effectively adjusted. When the absorber concentration is sufficiently high to clog the internal pores, the microwave absorption is hindered. When the filler (CoFe₂O₄/MXene-MF) content is just ∼5.8 wt % (at a density of ∼33.3 mg cm^-3), a minimum reflection loss (RL_min) of -72.1 dB is achieved at a matching thickness of 3.32 mm, and an effective absorption bandwidth (4.54 GHz) covering the whole X band is achieved at a thickness of 3 mm. CoFe₂O₄/MXene-MF, which possesses a 3D porous electromagnetic network structure, optimizes impedance matching and enhances multiple polarization relaxations and reflections/scattering, resulting in superior absorption capabilities. In particular, the continuous network structure ensures the uniform distribution of electromagnetic fields in the microstructure, achieving high absorption at low filler contents. This work provides a reference for subsequent 3D absorber concentration studies and a novel engineering strategy for preparing a low-filler-content, lightweight, and efficient electromagnetic wave absorber, which could be applied in the fields of radar security and information communications.