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Updated: Jul 3, 2025

Fabrication, Densification, and Replica Molding of 3D Carbon Nanotube Microstructures
Published on: July 2, 2012
Ti-B-O System for Catalyzing Boron Nitride Nanotube Growth
Qian He1, Liping Ding2, Xuhua He1
1National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, Jiangsu Key Laboratory of Artificial Functional Materials, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China.
Abstract:
Chemical vapor deposition (CVD) stands out as the most promising method for cost-effective production of high-quality boron nitride nanotubes (BNNTs). Catalysts play a crucial role in BNNT synthesis. This work delves into the impact of oxygen (O) on Ti-based catalysts during the CVD growth of BNNTs. In contrast to the B/TiB2 nanoparticles (NPs) and B/TiN NPs systems, the oxygen-containing precursor B/TiO2 NPs remarkably catalyzes the growth of high-quality and high-purity BNNTs across a wider range of synthesis parameters. Subsequent analyses reveal that TiBO3 acts as an active catalyst, facilitating BNNT growth in Ti-based catalyst systems. Moreover, the nanocomposite film synthesized from BNNTs and PVDF-HFP exhibits excellent mechanical properties and heat dissipation capabilities. Utilizing the nanocomposite film as a thermal interface material effectively enhances the heat dissipation for a 5 W light-emitting diode (LED) chip. Consequently, our research confirms the effectiveness of the Ti-B-O system in catalyzing BNNT growth.
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