Luminescent solvent-free liquids based on Schiff-base boron difluoride complexes with polyethylene glycol chains

A series of Schiff-base boron difluoride complexes with polyethylene glycol chains were synthesized and their photophysical properties were examined. These complexes maintained the solvent-free liquid state even at room temperature and their glass transition temperatures (T_g) were determined to be around -40 °C. The complexes showed blue to yellow luminescence under UV irradiation in the solvent-free liquid state with good emission quantum yields (Φ) of up to 0.26. The luminescence colour could also be tuned by dissolving organic dyes in the blue luminescent liquid sample. Density functional theory (DFT) and time-dependent (TD) DFT calculations were performed to further understand the photophysical properties.