The optical behavior of nano filled resin composite loaded with graphene oxide nanoparticles

Assessment of the effect of incorporation of graphene oxide nanoparticles (GONPs), different concentrations into resin composite with different thicknesses on its color modulation.

GONPs were prepared using the chemical reduction method and characterized using a transmission electron microscope and X-ray diffraction. The minimum concentrations of GONPs that provided the most effective antibacterial action (0.05 wt% and 0.2 wt%.) were prepared to be the concentration added to the tested resin composite. Calculations were done to find the required volume of the GONPs solution needed according to the mass of the resin composite. 70 nano-filled resin composite discs were prepared with 10 mm diameter × 3 mm height. 10 resin composite discs were prepared without GONPs incorporation and served as a control (G0). The other 60 resin composite specimens were divided into 2 equal groups (G1& G2) according to the concentration of the loaded nanoparticles in the specimens. Each group was divided into 3 equal subgroups according to the thickness of the resin composite containing GONPs; [T1: GONPs dispersed in the bottom 1 mm of the disc, while the top 2 mm of the disc was of resin composite only. T2: GONPs dispersed only in the bottom 2 mm of the disc and T3: GONPs dispersed in the total thickness of the disc (3 mm)]. ∆E values were calculated using a Vita Easy shade Spectrophotometer.

Incorporation of GONPs into resin composite induced significant color change and among all the 6 experimental groups, G1T1 group (of 0.05 wt% concentration GONPs dispersed only in the bottom 1 mm of the disc) showed a non-significant color change.

Dispersion of GONPs has a detectable effect on the color change of resin composite. Meanwhile, dispersion in low concentration for only the bottom 1 mm thickness of resin composite has an undetectable effect on its color.