Effects of natural and modified zeolite based composite fertilizers on slow release and nutrient use efficiency

Excessive use of chemical fertilizers causes serious environmental hazards, as only a fraction is really adsorbed by the soil. As part of the solution, the feasibility of using unmodified (UNZC) and surfactant-modified natural zeolite-based composite (SMNZC) fertilizers as support materials for the provision of nutrients to soil on a slow release basis was assessed using column and pot experiments. The characterization of the zeolite materials was done using powder XRD, XRF, SEM, BET, and TGA instruments. The percentage of cationic nutrients released from soil columns containing UNZC increased over time. Their release from SMNZC initially slowed down and became stable as the number of days increased. The percentage of N-NO₃^- and available P released from UNZC has constantly decreased with time. Their release from SMNZC increased as the number of days increased. The maximum P uptake by maize was observed for the soil treated with SMNZC, and there was no significant difference at all rates. The maximum uptake of Ca (3663.40 ppm), Mg (2617.34 ppm), and Fe (222.83 ppm) was observed at 250 kg/ha of UNZC. The highest uptake of K, Zn, and Cu was also observed for the soil amended with UNZC, irrespective of its application rate. Application of UNZC and SMNZC at the same rate equally affected total nitrogen uptake. Thus, this finding showed that UZNC is a better carrier of cationic nutrients, while SMNZC is preferable for the slow release of NO₃^- and available P. In conclusion, both the modified and unmodified support forms showed better performance than conventional fertilizer in delivering nutrients slowly and sustainably.