Effective chromium mitigation using phosphorous doped bio carbon electrode via capacitive deionisation

Capacitive deionisation (CDI) is an emerging eco-economic water reclamation technology that can remove inorganic salts and heavy metals. Biomass-derived carbon electrodes have attracted the scientific communities in recent years due to their economic feasibility and sustainability. However, electrochemical performance needs to be improved to achieve durability and reusability. Hence, the present study develops rice straw-derived phosphorous-doped (P-doped) carbon as an electrode for mitigating Cr(VI) ions. Phosphorus doping of biocarbon electrodes enhances their electrochemical properties, including increased electrical conductivity, improved charge storage capacity, and enhanced ion adsorption capabilities. Here, Phosphoric acid plays a dual role of activation and doping that enhances the physico-electrochemical properties. The synthesised material was found to be P-doped carbon with better pore distribution, which was confirmed through FESEM-EDX analysis. Further, the physicochemical properties of the electrode material are enriched with carbon and possess an enhanced surface area of 753 m²/g. The cyclic voltammetry shows the specific capacitance of 67 F/g for the Cr(VI) ions, which was found to be 15 times more than the non-doped carbon. CDI studies were performed with optimisation of operational parameters and found that mitigation of Cr(VI) ions was efficient at pH 2 for the applied voltage of 2V. The electrode's performance with real-time chrome wash effluent confirms its potentiality and has better scope upon optimisation. The experimental data fits well with pseudo first-order kinetics, which ensures the nature of electrosorption is physisorption.