Sol-Gel TiO₂ Thin Film on Au Nanoparticles for Heterogeneous Plasmonic Photocatalysis

A new, simple method for preparing substrates for photocatalytic applications under visible light is presented. It is based on the preparation of a dense array of gold nanoparticles (AuNPs) by thermal dewetting of a thin gold film followed by spin-coating of a thin TiO₂ film prepared by sol-gel chemistry. The photocatalytic properties of these nanocomposite films are studied by surface-enhanced Raman spectroscopy (SERS) following the N-demethylation reaction of methylene blue as a model reaction. This approach shows that the semiconducting layer on the AuNPs can significantly increase the efficiency of the photoinduced reaction. The SERS study also illustrates the influence of parameters such as TiO₂ thickness and position (on or under the AuNPs). Ultimately, this study emphasizes that the primary mechanism behind the N-demethylation reaction is both the increase in extinction and the improved electron transfer facilitated by the semiconducting layer. On the other hand, exclusive reliance on photothermal effects is ruled out.