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Updated: Jul 2, 2025

Simple Methods for the Preparation of Non-noble Metal Bulk-electrodes for Electrocatalytic Applications
Published on: June 21, 2017
Electrocatalytic Hydrogen Evolution of Immobilized Copper Complex on Carbonaceous Materials: From Neutral Water to
Chamniphol Taechaworaphong1, Methasit Juthathan1, Patchanita Thamyongkit1
1Department of Chemistry, Faculty of Science, Chulalongkorn University, Bangkok, Thailand.
Abstract:
Electrochemical hydrogen evolution reaction (HER) is an appealing strategy to utilize renewable electricity to produce green H2. Moreover, use of neutral-pH electrolyte such as water and seawater for the HER has long been desired for eco-friendly energy production that aligns with net zero emission goal. Herein, new heterogeneous catalysts were developed by dispersing an HER-active copper complex containing N4-Schiff base macrocycle (CuL) on carbonaceous materials, i. e. multi-walled carbon nanotube (CNT) and graphene oxide (GO), via non-covalent interaction and investigated their HER performance. It was found that CuL/GO exhibited higher HER activity than CuL/CNT, possibly due to its significantly larger amount of CuL immobilized onto GO. In addition, CuL/GO showed satisfactory HER performance in a neutral (pH 7) NaCl electrolyte solution. Notably, the performances of CuL/GO were boosted up when performed in natural seawater sample with the faradaic efficiency of 70 % and 3 times higher amount of H2 at -0.6 V vs reversible hydrogen electrode (RHE), in comparison to the HER in a NaCl electrolyte. Furthermore, it possessed a low overpotential of 139 mV at -10 mA/cm2. This demonstrated the potential use of CuL/GO as an effective HER catalyst in seawater for further sustainable development.
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