Selective lithium extraction from spent lithium-ion batteries through polyvinyl chloride thermal decomposition-based
Biyuan Yang1, Xinyu Lu2, Xiaowei Wang2
1Hunan Prevention and Treatment Institute for Occupational Diseases, Changsha, 410007, PR China.
Abstract:
The recovery of valuable metals from waste battery materials and the thermal decomposition of PVC both require significant energy and material consumption. In this study, we propose an innovative strategy that integrates the lithium extraction process from spent LiNi0.85Co0.15Al0.05O2 (S-NCA) with PVC pyrolysis, resulting in a substantial reduction in energy consumption and chemical additive. Various characterization techniques, including SEM, TEM, XRD, and XPS, are employed to investigate the mechanism of gas-solid lithium extraction and provide valuable insights into the migration pathway of lithium from S-NCA to soluble LiCl. The optimal conditions for the process were determined as follows: a temperature of 600 °C, S-NCA/PVC mass ratio of 1:4, and a baking time of 2 h, achieving a lithium extraction efficiency of 94.37 %. The research provides valuable insights for the valorization of PVC thermal decomposition and lithium extraction from NCA, presenting a novel approach for future applications.
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