Flexible Antireflection Coatings with Enhanced Durability and Antifogging Properties

Antireflection coatings (ARCs) enhance optical clarity and improve light transmission by reducing glare and reflections. The application of conventional ARCs in flexible devices, however, is impeded by their lack of durability, particularly under bending deformation. We develop ARCs that withstand delamination and fracture, remaining intact even after 1000 bending cycles with a 5 cm bending radius. We fabricate integrated ARCs (iARCs) on a poly(methyl methacrylate) (PMMA) substrate by inducing free polymers to infiltrate the interstices of a disordered assembly of hollow silica nanochains and nanospheres. The polydispersity of PMMA creates a refractive index gradient, yielding a broadband antireflection capability. The nanochain-based iARCs are superior to the nanosphere-based coatings in both antireflection properties and mechanical durability, owing to the lower packing density and mechanical interlocking of the nanochains, respectively. Additionally, these nanochain iARCs display antifogging properties stemming from their superhydrophilicity. While our demonstrations are based on PMMA as a model substrate, this methodology is potentially extendable to other polymers, enhancing the iARC's applicability across various practical applications, including flexible and wearable devices.