Promoting hydrophilic cupric oxide electrochemical carbon dioxide reduction to methanol via interfacial engineering...

Copper-based catalysts have been extensively investigated in electrochemical carbon dioxide (CO₂) reduction to promote carbon products generated by requiring multiple electron transfer. However, hydrophilic electrodes are unfavourable for CO₂ mass transfer and preferentially hydrogen (H₂) evolution in electrochemical CO₂ reduction. In this paper, a hydrophilic cupric oxide (CuO) electrode with a grassy morphology was prepared. CuO-derived Cu was confirmed as the active site for electrochemical CO₂ reduction through wettability modulation. To enhance the intrinsic catalytic activity, a metal-oxide heterogeneous interface was created by engineering modulation at the interface, involving the loading of palladium (Pd) on CuO (CuO/Pd). Both the electrochemically active area and the electron transfer rate were enhanced by Pd loading, and significantly the reduced work function further facilitated the electron transfer between the electrode surface and the electrolyte. Consequently, the CuO/Pd electrode exhibited excellent excellent performance in electrochemical CO₂ reduction, achieving a 54 % Faraday efficiency at -0.65 V for methanol (CH₃OH). The metal-oxide interfacial effect potentially improves the intrinsic catalytic activity of hydrophilic CuO electrodes in electrochemical CO₂ reduction, providing a conducive pathway for optimizing hydrophilic oxide electrodes in this process.