Related Experiment Video
Updated: Jul 2, 2025
Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
Published on: December 20, 2016
Disjoining Pressure Decay Length in Room-Temperature Ionic Liquids: A Molecular Simulation Study
Darya L Gurina1,2, Ekaterina G Odintsova1, Yury A Budkov1,2
1Laboratory of Multiscale Modeling of Molecular Systems, G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, Akademicheskaya St. 1, 153045 Ivanovo, Russian Federation.
Abstract:
We present all-atom molecular simulations to investigate the behavior of 1-ethyl-3-methylimidazolium tetrafluoroborate ([EMIM][BF4]) in negatively charged carbon nanopores of different widths (h = 5÷15 nm) and lengths (l = 4÷10 nm). The goal of our study was to determine how the disjoining pressure varies as a function of the pore width at different lengths and to understand the influence of edge effects. Our results show that the edge effect decreases as the pore length increases. Using an exponential function, we can approximate the disjoining pressure at large pore widths and use this approximation to estimate the decay length that can correlate with the electrostatic screening length. The results agreed well with those of previous experimental studies.
More Related Videos
06:44From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
Published on: March 24, 2018
08:54Vibrational Spectra of a N719-Chromophore/Titania Interface from Empirical-Potential Molecular-Dynamics Simulation, Solvated by a Room Temperature Ionic Liquid
Published on: January 25, 2020
Related Concept Videos
02:56Intermolecular Forces and Physical Properties
02:54Molecular and Ionic Solids
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
04:01Real Gases: Effects of Intermolecular Forces and Molecular Volume Deriving Van der Waals Equation
02:28Intermolecular Forces in Solutions
When the strengths of the intermolecular forces of attraction between solute and solvent species in a solution are no different than those present in the separated components, the solution is formed with no accompanying energy change. Such a solution is called an ideal solution. A mixture of ideal gases (or gases such as helium and argon,...
02:54Trends in Lattice Energy: Ion Size and Charge
02:55Solubility of Ionic Compounds