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Tailoring Multiple Strengthening Phases to Achieve Superior High-Temperature Strength in Cast Mg-RE-Ag Alloys
Sicong Zhao1, Erjun Guo1, Kun Liu1
1Key Laboratory of Advanced Manufacturing and Intelligent Technology (Ministry of Education), School of Material Science and Chemical Engineering, Harbin University of Science and Technology, Harbin 150080, China.
Abstract:
Mg alloys with excellent high-temperature mechanical properties are urgently desired to meet the design requirements of new-generation aircraft. Herein, novel cast Mg-10Gd-2Y-0.4Zn-0.2Ca-0.5Zr-xAg alloys were designed and prepared according to the advantages of multi-component alloying. The SEM and XRD results revealed that the as-cast microstructures contained α-Mg grains, β, and Zr-containing phase. As Ag rose from 0 wt.% to 2.0 wt.%, the grain size was refined from 40.7 μm to 33.5 μm, and the β phase significantly increased. The TEM observations revealed that the nano-scaled γ' phase could be induced to precipitate in the α-Mg matrix by the addition of Ag. The stacking sequence of lamellar γ' phases is ABCA. The multiple strengthening phases, including β phase, γ' phases, and Zr-containing particles, were effectively tailored through alloying and synergistically enhanced the mechanical properties. The ultimate tensile strength increased from 154.0 ± 3.5 MPa to 231.0 ± 4.0 MPa at 548 K when Ag was added from 0 to 2.0 wt.%. Compared to the Ag-free alloy, the as-cast alloy containing 2.0 wt.% Ag exhibited a minor reduction in ultimate tensile strength (7.0 ± 4.0 MPa) from 498 K to 548 K. The excellent high-temperature performance of the newly developed Mg-RE-Ag alloy has great value in promoting the use of Mg alloys in aviation industries.
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