Temperature-dependent decomposition of the CL-20/MTNP cocrystal after phase separation

CL-20 (2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane)-based cocrystals are attractive energetic cocrystals with a potential for high energy and low sensitivity, which account for nearly one-third of energetic cocrystals. The applications of cocrystal explosives require in-depth understanding of their thermal kinetics behaviors. Although thermal kinetics of the decomposition of CL-20-based cocrystals having no melting point have been studied, relevant research of CL-20-based cocrystals having a melting point, which are also the most frequently observed type, is still rare. In this study, the CL-20/MTNP (1-methyl-3,4,5-trinitropyrazole) cocrystal was chosen as a typical CL-20-based cocrystal having a melting point to investigate its thermal kinetics behavior. The thermal decomposition of CL-20/MTNP was identified to be a typical heterogeneous reaction with phase separation before decomposition. Due to the presence of intermolecular hydrogen bonds between CL-20 and molten MTNP after phase separation, the thermal decomposition behavior of CL-20/MTNP was strongly temperature-dependent. The complex decomposition reaction was separated into its three constituent pathways to simplify the kinetic analysis. On the basis of in-depth understanding of the decomposition process, the best functions of mechanism and kinetic parameters for each process of CL-20/MTNP decomposition were obtained using the model-fitting method. Finally, important thermal safety indicators, such as TMR_ad and SADT were simulated by combining the established kinetic models. This study provides further insights into the entire reaction process of the CL-20/MTNP cocrystal and would help in its better applications.