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Related Concept Videos

Entropy02:39

Entropy

30.2K
Salt particles that have dissolved in water never spontaneously come back together in solution to reform solid particles. Moreover, a gas that has expanded in a vacuum remains dispersed and never spontaneously reassembles. The unidirectional nature of these phenomena is the result of a thermodynamic state function called entropy (S). Entropy is the measure of the extent to which the energy is dispersed throughout a system, or in other words, it is proportional to the degree of disorder of a...
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Entropy Change in Reversible Processes01:10

Entropy Change in Reversible Processes

2.5K
In the Carnot engine, which achieves the maximum efficiency between two reservoirs of fixed temperatures, the total change in entropy is zero. The observation can be generalized by considering any reversible cyclic process consisting of many Carnot cycles. Thus, it can be stated that the total entropy change of any ideal reversible cycle is zero.
The statement can be further generalized to prove that entropy is a state function. Take a cyclic process between any two points on a p-V diagram.
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Entropy and Solvation02:05

Entropy and Solvation

7.1K
The process of surrounding a solute with solvent is called solvation. It involves evenly distributing the solute within the solvent. The rule of thumb for determining a solvent for a given compound is that like dissolves like. A good solvent has molecular characteristics similar to those of the compound to be dissolved. For example, polar solutions dissolve polar solutes, and apolar solvents dissolve apolar solutes. A polar solvent is a solvent that has a high dielectric constant (ϵ...
7.1K
Entropy and the Second Law of Thermodynamics01:20

Entropy and the Second Law of Thermodynamics

2.8K
The second law of thermodynamics can be stated quantitatively using the concept of entropy. Entropy is the measure of disorder of the system.
The relation  between entropy and disorder can be illustrated with the example of the phase change of ice to water. In ice, the molecules are located at specific sites giving a solid state, whereas, in a liquid form, these molecules are much freer to move. The molecular arrangement has therefore become more randomized. Although the change in average...
2.8K
¹H NMR of Conformationally Flexible Molecules: Temporal Resolution00:52

¹H NMR of Conformationally Flexible Molecules: Temporal Resolution

839
At room temperature, the chair conformer of cyclohexane undergoes rapid ring flipping between two equivalent chair conformers at a rate of approximately 105 times per second. These two chair conformers are in equilibrium. The rapid ring flipping results in the interconversion of the axial proton to an equatorial proton and an equatorial to the axial proton. Such interconversions are too rapid and cannot be detected on the NMR timescale. Hence, the NMR spectrometer cannot distinguish between the...
839
Third Law of Thermodynamics02:38

Third Law of Thermodynamics

18.9K
A pure, perfectly crystalline solid possessing no kinetic energy (that is, at a temperature of absolute zero, 0 K) may be described by a single microstate, as its purity, perfect crystallinity,and complete lack of motion means there is but one possible location for each identical atom or molecule comprising the crystal (W = 1). According to the Boltzmann equation, the entropy of this system is zero.
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An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
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Mesoscopic fluctuations in entanglement dynamics.

Lih-King Lim1, Cunzhong Lou1, Chushun Tian2

  • 1School of Physics, Zhejiang University, 310027, Hangzhou, Zhejiang, China.

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Researchers discovered emergent random structures in quantum systems, leading to unique entanglement fluctuations. These fluctuations follow universal scaling laws and have implications for quantum device control.

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Area of Science:

  • Many-body physics
  • Quantum information theory
  • Condensed matter physics

Background:

  • Fluctuation phenomena are crucial in many-body physics.
  • Time evolution of entanglement is key to understanding quantum matter and thermalization.
  • Entanglement fluctuations differ from traditional out-of-equilibrium fluctuations and are challenging to study.

Purpose of the Study:

  • To uncover emergent random structures in many-body wavefunction evolution.
  • To characterize out-of-equilibrium entanglement fluctuations in integrable lattice models.
  • To investigate the universality and implications of these fluctuations.

Main Methods:

  • Analysis of two classes of integrable lattice models (interacting and noninteracting).
  • Study of the time evolution of the many-body wavefunction.
  • Investigation of entanglement entropy variance and full distribution statistics.

Main Results:

  • An emergent random structure was found in wavefunction evolution.
  • Out-of-equilibrium entanglement fluctuations exhibit mesoscopic characteristics.
  • Entanglement entropy variance follows a universal scaling law.
  • The full distribution shows sub-Gaussian upper and sub-Gamma lower tails, independent of microscopic details and probes.

Conclusions:

  • Entanglement fluctuations in integrable models fall under mesoscopic fluctuation paradigms.
  • The observed statistics broaden the understanding of mesoscopic universalities.
  • Findings have practical implications for controlling entanglement in mesoscopic devices.