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Updated: Jul 2, 2025
Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of ChalcogenidoplumbatesII or IV
Published on: December 29, 2016
Ligand engineering to achieve synergistic properties in a 2D bilayer supertetrahedral chalcogenide cluster-based
Yan-Ling Li1, Yu-Dong Liu1, Wei-Li Li1
1School of Chemical and Environmental Engineering, Pingdingshan University, Pingdingshan 467000, China. liyanling16@126.com.
Abstract:
Incorporating functional organic linkers into supertetrahedral chalcogenolate cluster-based materials is an effective synthetic strategy to expand structural diversity and generate tunable optical and photoelectric properties arising from synergistic effects. Herein, a mixed ligand engineering approach was adopted to design a supertetrahedral cluster-based assembled material [(Cd6Ag4(SPh)16(TPPA)(BPE)0.5)·2DMF] (denoted as SCCAM-3) with a 2D bilayer architecture and broader visible-light absorption. Interestingly, SCCAM-3 demonstrates a long-lived afterglow at 83 K and efficient photocatalytic activity for degrading tetracycline in water.
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