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Portable smartphone platform utilizing AIE-featured carbon dots for multivariate visual detection for Cu2+, Hg2+ and
Yunqi Hao1, Fangyan Ji1, Tingting Li1
1Key Laboratory of Photochemical Biomaterials and Energy Storage Materials, Heilongjiang Province, Key Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, College of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150025, Heilongjiang Province, China.
Abstract:
Heavy metals cause serious toxic threats to both environment and human health. The multivariate, instrument-free, portable, and rapid detection strategy is crucial for determination of heavy metals. Herein, aggregation-induced emission (AIE) featured carbon dots (SN-CDs) were fabricated hydrothermally by optimizing co-doping precursors. With bright yellow emission at 560 nm, the SN-CDs were utilized for multivariate sensing Cu2+, Hg2+ and bovine serum albumin (BSA) based on AIE behavior and static quenching effect, with detection limits of 0.46 μmol·L-1, 25.8 nmol·L-1 and 1.52 μmol·L-1. A portable smartphone platform was constructed to enable portable, prompt, and sensitive analysis for Cu2+, Hg2+, and BSA via different strategies in real water and food samples with satisfied recovery. Moreover, a logic gate circuit was designed to provide the possibilities for utilization of intelligent facility. The proposed AIE SN-CDs possessing great contribution in preferable sensing performance, present promising prospects in real-time monitoring of environment and food safety.

