Enhanced Role of Streamflow Processes in the Evolutionary Trends of Dissolved Organic Carbon

Investigating dissolved organic carbon (DOC) dynamics and drivers in rivers enhances the understanding of carbon-environment linkages and support sustainability. Previous studies did not fully consider the dynamic nature of key drivers that influence the long-term changing trends in DOC concentration over time (the controlling factors and their roles in DOC trend can undergo alterations over time). We analyzed 42 years (1979-2018) of hydrometeorology, sulfate SO₄, and DOC data from a 5.42 km² watershed in central-southern Ontario, Canada. Our findings reveal a significant (p ≤ 0.01) overall increase in DOC concentrations, mainly due to the coevolution of SO₄ and streamflow trends, especially the extreme flows. Over the 42-year period, the changing trend of streamflow (especially the extreme high or low flows) have significantly (p < 0.05) intensified their influence on DOC trends, increasing by an average of 30%. Conversely, the impact of SO₄ has weakened, experiencing an average decrease of 32.6%. The upward trend in the annual average DOC concentration is attributed to the increasing number of maximum flow days within a year, while the decreasing trend in the number of minimum flow days has a contrasting effect. In other words, changes in maximum and minimum flow days have a counteracting effect on the DOC concentration trends. These results underscore the importance of considering the effects of altered streamflow processes on carbon cycle changes under evolving environmental conditions.