Related Experiment Video
Updated: Jul 1, 2025
Synthesis of a Borylated Ibuprofen Derivative Through Suzuki Cross-Coupling and Alkene Boracarboxylation Reactions
Published on: November 30, 2022
Boryls, their compounds and reactivity: a structure and bonding perspective
1Department of Chemistry, The Hong Kong University of Science and Technology Clear Water Bay Kowloon Hong Kong chzlin@ust.hk.
Abstract:
Boryls and their compounds are important due to their diverse range of applications in the fields of materials science and catalysis. They are an integral part of boron chemistry, which has attracted tremendous research interest over the past few decades. In this perspective, we provide an in-depth analysis of the reaction chemistry of boryl compounds from a structure and bonding perspective. We discuss the reactivity of boryls in various transition metal complexes and diborane(4) compounds towards different substrate molecules, with a focus on their nucleophilic and electrophilic properties in various reaction processes. Additionally, we briefly discuss the reactivity of boryl radicals. Our analysis sheds new light on the unique properties of boryls and their potential for catalytic applications.
Related Concept Videos
01:23Properties of Organometallic Compounds
02:16Resonance and Hybrid Structures
Resonance Structures and Resonance Hybrids
The Lewis structure of a nitrite anion (NO2−) may actually be drawn in two different ways, distinguished by the locations of the N–O and N=O bonds.
02:36Regioselectivity and Stereochemistry of Hydroboration
Hydroboration proceeds in a concerted fashion with the attack of borane on the π bond, giving a cyclic four-centered transition state. The –BH2 group is bonded to the less substituted carbon and –H to the more substituted carbon. The concerted nature requires the simultaneous addition of –H and –BH2 across the same face of the alkene giving syn...
03:51Molecular Orbital Theory II
02:55Exceptions to the Octet Rule
03:08Hydroboration-Oxidation of Alkenes