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  1. Home
  2. The Effects Of Delayed Annealing On The Luminescent Activity Of Heavy Metal Cadmium Zinc Phosphate Glasses Activated By: Er3+ And Tb3+ Ions.
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  2. The Effects Of Delayed Annealing On The Luminescent Activity Of Heavy Metal Cadmium Zinc Phosphate Glasses Activated By: Er3+ And Tb3+ Ions.

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The effects of delayed annealing on the luminescent activity of heavy metal cadmium zinc phosphate glasses activated

M A Marzouk1, F H Elbatal2, H A Elbatal2

  • 1Glass Research Department, National Research Centre, 33 El Bohouth Street (former EL Tahrir), Dokki, P.O. 12622, Giza, Egypt. marzouk_nrc@yahoo.com.

Scientific Reports
|March 1, 2024

View abstract on PubMed

Summary
This summary is machine-generated.

Rare-earth-doped phosphate glasses containing erbium (Er) and terbium (Tb) exhibit enhanced green light emission. Annealing temperature and rare-earth concentration significantly impact luminescence performance.

Keywords:
AnnealingGlassHeavy metal oxideLuminescencePhosphateRare-Earth

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Area of Science:

  • Materials Science
  • Solid State Chemistry
  • Luminescence

Background:

  • Rare-earth-doped glasses are crucial for optical applications.
  • Understanding the influence of dopants and processing on luminescence is essential.

Purpose of the Study:

  • To investigate the luminescent properties of Er2O3- and Tb2O3-doped P2O5-CdO-ZnO glasses.
  • To determine the effects of rare-earth elements and annealing on emission performance.

Main Methods:

  • UV-visible absorption spectroscopy
  • Luminescence spectroscopy
  • Thermal expansion analysis
  • X-ray diffraction (XRD)
  • Transmission electron microscopy (TEM)
  • Fourier-transform infrared spectroscopy (FTIR)

Main Results:

  • Er3+ and Tb3+ ions exhibit characteristic green light emission under UV excitation.
  • Emission intensity is enhanced by increasing rare-earth concentration and annealing temperature.
  • Er3+ shows infrared emission at 1532 nm, potentially influenced by heating.
  • Phosphate groups in the glass structure remain largely stable.

Conclusions:

  • The study successfully separated the effects of Er and Tb on glass luminescence.
  • Optimized annealing and rare-earth doping can enhance luminescence properties.
  • These glasses show potential for applications requiring specific light emission characteristics.