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Updated: Jul 1, 2025

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
Published on: December 16, 2022
Recyclable Curcumin-Based Bioepoxy Resin with On-Demand Chemical Cleavability
Jisu Jeong1, Yeonha Ju1, Younggi Hong1
1Department of Chemical Engineering, Konkuk University, Gwangjin, Seoul 05029, Republic of Korea.
Abstract:
We synthesized a novel curcumin-based bioepoxy resin by introducing epichlorohydrin (ECH) into the hydroxyl groups of curcumin and analyzed it using Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (NMR). The epoxy equivalent weight (EEW) was determined based on a reaction with sodium hydroxide (NaOH) through titration, and the actual curing process was conducted after exploring the optimal conditions using an amine-based curing agent through dynamic scanning in differential scanning calorimetry (DSC) and isotherm analysis. The cured epoxy resin had a tensile strength, Young's modulus, and glass transition temperature (Tg) of 33 MPa, 1.4 GPa, and 86 °C, respectively. Interestingly, the diunsaturated ketone contained in the epoxy resin showed on-demand chemical cleavability, in that it had been decomposed into an aldehyde and ketone only after having been converted to a hydroxyl ketone through an oxidation reaction. The results of this study can significantly contribute to improving the eco-friendliness and recyclability of epoxy resins used in fields requiring long-term stability and chemical resistance.
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