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N,N'-Diaryl-Sulfurdiimides are Strongly Redox Tuned

Nathan D D Hill1, René T Boeré1

  • 1Department of Chemistry and Biochemistry and The Canadian Centre for Research in Advanced Fluorine Technologies, University of Lethbridge, 4401 University Dr. W, Lethbridge, AB, Canada, T1K3M4.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|March 5, 2024
PubMed
Summary

This study details nine aryl sulfur diimides (SDIs), revealing their tunable electrochemical properties. Substituent effects strongly influence reduction potentials, correlating with computed orbital energies, offering new insights into thiazyl chemistry.

Keywords:
DFT computationEPR spectroelectrochemistrySC-XRD structure determinationUV-vis spectroscopychemical synthesiselectrochemistryinfrared spectroscopythiazyl chemistry

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