Related Experiment Video
Updated: Jul 1, 2025

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
Published on: April 9, 2018
Electrochemical Synthesis of Selenosulfonates from Diselenides and Sulfonyl Hydrazides
Jin-Feng Lv1, Yang Deng1, Xin-Yi Liang1
1Key Laboratory of Applied Chemistry of Chongqing Municipality, School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China.
Abstract:
The electrochemical oxidative radical-radical cross-coupling of sulfonyl hydrazides with diselenides for the synthesis of selenosulfonates was successfully accomplished. The method is applicable to a wide range of aromatic/aliphatic sulfonyl hydrazides and diselenides, providing products in good to excellent yields. Notably, this protocol stands out for its green and sustainable nature, as it does not rely on transition metals and oxidizing agents, and the starting materials are cost-effective and readily available.
More Related Videos
Related Concept Videos
Preparation and Reactions of Sulfides
Preparation and Reactions of Thiols
Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide
Electrophilic Aromatic Substitution: Sulfonation of Benzene
Diazonium Group Substitution with Halogens and Cyanide: Sandmeyer and Schiemann Reactions
Structure and Nomenclature of Thiols and Sulfides
![The Synthesis of [Sn10SiSiMe334]2- Using a Metastable SnI Halide Solution Synthesized via a Co-condensation Technique](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F54498.jpg&w=3840&q=50)
