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Quantum tomography of molecules using ultrafast electron diffraction.

Jiayang Jiang1, Ming Zhang2, Aosheng Gu1

  • 1Departments of Chemistry and Physics, University of Toronto, Toronto, Ontario M5S 3H6, Canada.

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|March 8, 2024
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Summary

We developed a quantum tomography method to reconstruct molecular electronic states from ultrafast electron diffraction. This technique allows visualizing electronic dynamics, like a "molecular movie," capturing coherence and population transfer.

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Area of Science:

  • Quantum Chemistry
  • Spectroscopy
  • Chemical Physics

Background:

  • Ultrafast electron diffraction (UED) probes molecular dynamics.
  • Reconstructing electronic state evolution from UED is challenging.

Purpose of the Study:

  • To develop a quantum tomography (QT) approach for retrieving time-evolving reduced density matrices.
  • To visualize electronic degrees of freedom in molecular dynamics using UED.

Main Methods:

  • Simulated nuclear wavepacket dynamics and UED of photoexcited pyrrole using ab initio CASSCF.
  • Applied QT to reconstruct the density matrix from simulated time-resolved diffraction data.

Main Results:

  • Successfully retrieved the evolving density matrix in a diabatic basis.
  • Revealed the symmetry of the excited pyrrole wavepacket.
  • Demonstrated QT's capability to capture electronic state coherence and population transfer.

Conclusions:

  • The proposed QT approach enables quantum-level "molecular movies" of electronic dynamics.
  • UED can now reveal electronic state coherence, relaxation, and population transfer dynamics.