Switching reactive oxygen species reactions derived from Mn-Pt anchored zeolite for selective catalytic ozonation

Rationally switching reactive oxygen species (ROS) reactions in advanced oxidation processes (AOPs) is urgently needed to improve the adaptability and efficiency for the engineering application. Herein we synthesized bimetallic Mn-Pt catalysts based on zeolite to realize the switching of ROS reactions in catalytic ozonation for sustainable degradation of organic pollutants from water. The ROS reactions switched from singlet oxygen (¹O₂, 71.01%) to radical-dominated (93.79%) pathway by simply introducing defects and changing Pt/Mn ratios. The oxygen vacancy induced by anchoring Mn-Pt species from zeolite external surface (MnPt/H-Beta) to internal framework (MnPt@Si-Beta) exposes more electron-rich Pt²⁺/Pt⁴⁺ redox sites, accelerating the decomposition of O₃ to generate •OH via electron transfer and switching ROS reactions. The Mn site acted as a bridge plays a critical role in conducting electrons from organic pollutants to Pt sites, which solidly solves the electron loss of catalysts, facilitating the efficient degradation of pollutants. A 34.7-fold increase in phenol degradation compared with the non-catalytic ozonation and an excellent catalytic stability are achieved by MnPt@Si-Beta/O₃. The ¹O₂-dominated ROS reaction originated from MnPt/H-Beta/O₃ exhibits superior performances in anti-interference for Cl^-, HCO₃^-, NO₃^-, and SO₄^-. This work establishes a novel strategy for switching ROS reactions to expand the targeted applications of O₃ based AOPs for environmental remediation.