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Related Concept Videos

Ionic Crystal Structures02:42

Ionic Crystal Structures

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Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
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In a precipitation reaction, aqueous solutions of soluble salts react to give an insoluble ionic compound – the precipitate. The reaction occurs when oppositely charged ions in solution overcome their attraction for water and bind to each other, forming a precipitate that separates out from the solution. Since such reactions involve the exchange of ions between ionic compounds in aqueous solution, they are also referred to as double displacement, double replacement, exchange reactions, or...
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Ionic Bonding and Electron Transfer02:48

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Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
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Ionic Compounds: Formulas and Nomenclature03:34

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An element composed of atoms that readily lose electrons (a metal) can react with an element composed of atoms that readily gain electrons (a nonmetal) to produce ions through complete electron transfer. The compound formed by this transfer is stabilized by the electrostatic attractions (ionic bonds) between the oppositely charged ions.
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Coordination Compounds and Nomenclature02:54

Coordination Compounds and Nomenclature

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In most main group element compounds, the valence electrons of the isolated atoms combine to form chemical bonds that satisfy the octet rule. For instance, the four valence electrons of carbon overlap with electrons from four hydrogen atoms to form CH4. The one valence electron leaves sodium and adds to the seven valence electrons of chlorine to form the ionic formula unit NaCl (Figure 1a). Transition metals do not normally bond in this fashion. They primarily form coordinate covalent bonds, a...
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Electron Affinity

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The electron affinity (EA) is the energy change for adding an electron to a gaseous atom to form an anion (negative ion).
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Nitridochromate(IV) fluoride - LiCa8[CrN3]2N2F.

Natalia Gloriozova1, Yurii Prots1, Mitja Krnel1

  • 1Max-Planck-Institut für Chemische Physik fester Stoffe, Nöthnitzer Straße 40, 01187, Dresden, Germany. Peter.Hoehn@cpfs.mpg.de.

Dalton Transactions (Cambridge, England : 2003)
|March 11, 2024
PubMed
Summary

Researchers synthesized a novel multinary nitridochromate fluoride, LiCa8[CrIVN3]2N2F, confirming the presence of tetravalent chromium (Cr(IV)). This semiconductor material exhibits a 1.1 eV band gap, offering insights into elusive Cr(IV) compounds.

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Area of Science:

  • Inorganic Chemistry
  • Solid-State Chemistry
  • Materials Science

Background:

  • Tetravalent nitridochromates are rare and poorly understood.
  • Previous studies focused on trivalent chromium compounds.

Purpose of the Study:

  • To synthesize and characterize a novel multinary nitridochromate fluoride.
  • To provide further information on tetravalent nitridochromates.
  • To investigate the electronic and structural properties of the new compound.

Main Methods:

  • Single crystal X-ray diffraction for structure determination.
  • Magnetic susceptibility measurements to assess magnetic behavior.
  • Vibrational spectroscopy (e.g., IR, Raman) for structural and bonding insights.
  • Band structure calculations for electronic properties.

Main Results:

  • Synthesis and crystal structure determination of LiCa8[CrIVN3]2N2F (space group Pnnm).
  • Evidence for Cr(IV) oxidation state supported by shorter Cr-N bonds, diamagnetism, and spectroscopy.
  • Band structure calculations indicate a semiconductor with a 1.1 eV band gap.
  • The compound features trigonal planar [CrN3]5 units.

Conclusions:

  • LiCa8[CrIVN3]2N2F is a stable semiconductor containing tetravalent chromium.
  • The study expands the knowledge of nitridochromate chemistry.
  • The material's properties make it a candidate for further electronic applications.