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Microwave engineered NiZrO3@GNP as efficient electrode material for energy storage applications
J John Benitto1, J Judith Vijaya1, B Saravanakumar2
1Catalysis and Nanomaterials Research Laboratory, Department of Chemistry, Loyola College Chennai-600034 Tamil Nadu India.
RSC Advances
|March 12, 2024
Summary
A novel microwave-engineered NiZrO3@GNP composite shows promise as a supercapacitor electrode material, offering high specific capacity and good cyclic stability for advanced energy storage applications.
Area of Science:
- Materials Science
- Electrochemistry
- Nanotechnology
Background:
- Supercapacitors (SCs) require advanced electrode materials for enhanced performance.
- High-power density, rapid charge/discharge, and long cycle life are key SC metrics.
- Developing innovative materials is crucial for meeting future energy storage demands.
Purpose of the Study:
- To explore the potential of microwave-engineered NiZrO3@GNP composite as a supercapacitor electrode.
- To fabricate and characterize the NiZrO3@GNP nanocomposite using a microwave-assisted hydrothermal method.
- To evaluate the electrochemical performance of the composite in an asymmetric supercapacitor device.
Main Methods:
- Microwave-assisted hydrothermal synthesis of NiZrO3@GNP nanocomposite.
- Structural and morphological characterization of the synthesized material.
- Electrochemical testing of the NiZrO3@GNP composite as an electrode in a two-electrode asymmetric supercapacitor device.
Main Results:
- The NiZrO3@GNP composite exhibited battery-like behavior with a high specific capacity of 577.63 C g⁻¹.
- The asymmetric SC device using NiZrO3@GNP demonstrated a specific capacity of 47 C g⁻¹.
- The device maintained 70% capacitance retention after 2000 charge-discharge cycles, indicating good cyclic stability.
Conclusions:
- Microwave-engineered NiZrO3@GNP composite is a promising electrode material for high-performance supercapacitors.
- The material demonstrates excellent electrochemical properties, including high capacity and stability.
- Further optimization of synthesis and device configuration could lead to even greater advancements in supercapacitor technology.

