Synthesis and Study of SrTiO₃/TiO₂ Hybrid Perovskite Nanotubes by Electrochemical Anodization

Layers of TiO₂ nanotubes formed by the anodization process represent an area of active research in the context of innovative energy conversion and storage systems. Titanium nanotubes (TNTs) have attracted attention because of their unique properties, especially their high surface-to-volume ratio, which makes them a desirable material for various technological applications. The anodization method is widely used to produce TNTs because of its simplicity and relative cheapness; the method enables precise control over the thickness of TiO₂ nanotubes. Anodization can also be used to create decorative and colored coatings on titanium nanotubes. In this study, a combined structure including anodic TiO₂ nanotubes and SrTiO₃ particles was fabricated using chemical synthesis techniques. TiO₂ nanotubes were prepared by anodizing them in ethylene glycol containing NH₄F and H₂O while applying a voltage of 30 volts. An anode nanotube array heat-treated at 450 °C was then placed in an autoclave filled with dilute SrTiO₃ solution. Scanning electron microscopy (SEM) analysis showed that the TNTs were characterized by clear and open tube ends, with an average outer diameter of 1.01 μm and an inner diameter of 69 nm, and their length is 133 nm. The results confirm the successful formation of a structure that can be potentially applied in a variety of applications, including hydrogen production by the photocatalytic decomposition of water under sunlight.