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Related Concept Videos

Chemical Equilibria: Redefining Equilibrium Constant01:20

Chemical Equilibria: Redefining Equilibrium Constant

589
The effect of an inert salt on the solubility of a sparingly soluble salt is known as the salt effect. The degree of the salt effect varies with the ionic strength of the solution, which in turn depends on the activity of the species in the solution. The activity is expressed as the product of concentration and the activity coefficient of the species.
To calculate the equilibrium constants of solutions of moderately high ionic strength, one must account for the salt effect. This redefined...
589
Le Chatelier's Principle: Changing Temperature02:19

Le Chatelier's Principle: Changing Temperature

29.6K
Consistent with the law of mass action, an equilibrium stressed by a change in concentration will shift to re-establish equilibrium without any change in the value of the equilibrium constant, K. When an equilibrium shifts in response to a temperature change, however, it is re-established with a different relative composition that exhibits a different value for the equilibrium constant.
To understand this phenomenon, consider the elementary reaction:
29.6K
Le Chatelier's Principle: Changing Concentration02:27

Le Chatelier's Principle: Changing Concentration

58.4K
A system at equilibrium is in a state of dynamic balance, with forward and reverse reactions taking place at equal rates. If an equilibrium system is subjected to a change in conditions that affects these reaction rates differently (a stress), then the rates are no longer equal and the system is not at equilibrium. The system will subsequently experience a net reaction in the direction of a greater rate (a shift) that will re-establish the equilibrium. This phenomenon is summarized by Le...
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The Equilibrium Constant03:11

The Equilibrium Constant

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Consider the oxidation of sulfur dioxide:
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Solution Equilibrium and Saturation01:59

Solution Equilibrium and Saturation

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Imagine adding a small amount of sugar to a glass of water, stirring until all the sugar has dissolved, and then adding a bit more. You can repeat this process until the sugar concentration of the solution reaches its natural limit, a limit determined primarily by the relative strengths of the solute-solute, solute-solvent, and solvent-solvent attractive forces. You can be certain that you have reached this limit because, no matter how long you stir the solution, undissolved sugar remains. The...
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Chemical Equilibria: Systematic Approach to Equilibrium Calculations01:21

Chemical Equilibria: Systematic Approach to Equilibrium Calculations

699
Equilibrium calculations for systems involving multiple equilibria are often complex. For example, to calculate the solubility of a sparingly soluble salt in an aqueous solution in the presence of a common ion, one must consider all the equilibria in this solution. Calculations for these systems can be complicated and tedious, so a systematic approach with a series of steps is often helpful. The process is detailed below.
The first step is to identify all the chemical reactions involved, The...
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Related Experiment Video

Updated: Jun 30, 2025

Accurate Determination of the Equilibrium Surface Tension Values with Area Perturbation Tests
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Accurate Determination of the Equilibrium Surface Tension Values with Area Perturbation Tests

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When an active bath behaves as an equilibrium one.

Shubhendu Shekhar Khali1, Fernando Peruani2, Debasish Chaudhuri1,3

  • 1Institute of Physics, Sachivalaya Marg, Bhubaneswar 751005, India.

Physical Review. E
|March 16, 2024
PubMed
Summary
This summary is machine-generated.

Inertia in active Brownian particle systems leads to equilibrium-like behavior, with normal velocity distributions and mass-dependent diffusivity. This contrasts with overdamped systems, restoring the Einstein relation.

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Area of Science:

  • Statistical Mechanics
  • Soft Matter Physics
  • Active Matter Physics

Background:

  • Active Brownian particles exhibit non-Gaussian velocity distributions in overdamped systems.
  • Kinetic temperature and diffusion coefficients typically scale with the square of active velocity (v₀²).

Purpose of the Study:

  • Investigate the impact of inertial effects on active Brownian particle systems.
  • Analyze how mass influences diffusivity, mobility, and velocity distributions.
  • Determine if equilibrium properties are recovered in inertial active systems.

Main Methods:

  • Theoretical analysis of inertial active Brownian particle dynamics.
  • Derivation of velocity distributions and transport coefficients.
  • Examination of scaling behaviors with active velocity and particle mass.

Main Results:

  • Inertial effects lead to normal velocity distributions, unlike overdamped systems.
  • Kinetic temperature and diffusion coefficient scale as ∼v₀^α (1<α<2).
  • Late-time diffusivity and mobility decrease with increasing particle mass.
  • The equilibrium Einstein relation is asymptotically recovered with inertia.

Conclusions:

  • Inertial mass restores equilibrium-like behavior in active matter systems.
  • Mass-dependent diffusivity and mobility highlight the role of inertia.
  • Findings challenge the universal non-Gaussian nature of active particle dynamics.