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Updated: Jun 30, 2025

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs
Published on: January 17, 2020
Experimental and theoretical insights for designing Zn2+ complexes to trigger chemo-selective hetero-coupling of
Arup Samanta1, Prativa Behera2, Amit Chaubey1
1Department of Chemistry, Indian Institute of Technology-Guwahati, Kamrup, Assam 781039, India. dsrimani@iitg.ac.in.
Abstract:
Designing well-defined Zn-complexes for sustainable dehydrogenative catalysis overcoming the difficulties associated with activating Zn2+(d10)-metal species is considered paramount goal in catalysis. Herein, we explore the plausibility of β-alkylation of secondary alcohols with primary alcohols by well-defined 3d10 Zn-complexes. Detailed organometallic and catalytic investigations, in conjunction with computational analyses, were conducted to ascertain the potential involvement of the catalyst at various stages of the catalytic process.
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