Coincidence mass spectrometry study of double ionization of pyrene by 70 eV electron impact

We have performed coincidence mass spectrometry of fragmentation of pyrene molecules by 70 eV electron impact. Ionized fragments have been mass selected using a reflectron time-of-flight mass spectrometer, and a field programmable gate array has been used for the timing of the electron and ion extraction pulses and for the event-by-event detection of the ions. Double ionization results in a number of prominent fragmentations producing two singly-ionized fragments with kinetic energies of up to a few eV. A number of fragmentations produce ions with four or more carbon atoms, which can only be formed by the breaking of at least three C-C bonds.