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Synthesis and Structure of Protonated Sulfur Dioxide
Christoph Jessen1, Andreas J Kornath1
1Department of Chemistry, Ludwig-Maximilian University of Munich, Butenandtstr. 5-13, 81377, München, Germany.
Abstract:
Salts of protonated sulfur dioxide were synthesized by recrystallization of [FS(OX)2][SbF6] (X=H, D) in aprotic solvents at low temperatures. Hemiprotonated sulfur dioxide [(SO2)2H][Sb2F11] was obtained from the solvent SO2 and the monoprotonated sulfur dioxide [OSOD][Sb2F11], using 1,1,1,2-tetrafluoroethane as solvent. For both compounds, single crystals were obtained and an X-ray structure analysis was conducted. Furthermore, the salts were characterized by Raman spectroscopy and the results were discussed together with quantum chemical calculations on the M06-2X/aug-cc-pVTZ level of theory.
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