Algae removal and algal organic matter chemistry modulated by KMnO₄-PAC in simulated karst water

In this study, we examined the modulation of algae removal and algal organic matter (AOM) chemistry by potassium permanganate and poly-aluminum chloride (KMnO₄-PAC) in simulated karst water. Specifically, we verified the compositional changes of AOM sourcing from Chlorella sp. and Pseudanabaena sp. in response to the presence of divalent ions (Ca²⁺ and Mg²⁺). Aromatic protein and soluble microbial products were identified as the primary AOM components. Divalent ions accelerated dissolved organic carbon (DOC) and UV₂₅₄ removal, particularly with Pseudanabaena sp. greater than Chlorella sp. (P < 0.05). Surface morphology analysis manifested that the removal of filamentous Pseudanabaena sp. was more feasible in comparison to globular Chlorella sp.. Our results highlight the significance of divalent ions in governing chemical behaviors and subsequent removal of both algae and AOM. This study upscales the understanding of the interactions among divalent ions, algae and AOM during preoxidation and coagulation process in algae-laden karst water.