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Coplanar Forces01:25

Coplanar Forces

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Consider an object upon which multiple forces are acting. If the lines of action of each force lie within the same plane, the system can be considered coplanar. The Cartesian vector form can be used to resolve each force into its respective components. For a coplanar system, the system will be in equilibrium if each component of the resultant force equals zero and the resultant force on the system is zero. If the sum of the forces is not equal to zero, then the object will not be in equilibrium...
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Gauss's Law: Cylindrical Symmetry01:20

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A charge distribution has cylindrical symmetry if the charge density depends only upon the distance from the axis of the cylinder and does not vary along the axis or with the direction about the axis. In other words, if a system varies if it is rotated around the axis or shifted along the axis, it does not have cylindrical symmetry. In real systems, we do not have infinite cylinders; however, if the cylindrical object is considerably longer than the radius from it that we are interested in,...
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Mohr's Circle for Moments of Inertia: Problem Solving01:14

Mohr's Circle for Moments of Inertia: Problem Solving

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Mohr's circle is a graphical method for determining an area's principal moments by plotting the moments and product of inertia on a rectangular coordinate system. This circle can also be used to calculate the orientation of the principal axes.
Consider a rectangular beam. The moments of inertia of the beam about the x and y axis are 2.5(107) mm4 and 7.5(107) mm4, respectively. The product of inertia is 1.5(107) mm4. Determine the principal moments of inertia and the orientation of the major and...
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Dynamics Of Circular Motion: Applications01:17

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Suppose a car moves on flat ground and turns to the left. The centripetal force causing the car to turn in a circular path is due to friction between the tires and the road. For this, a minimum coefficient of friction is needed, or the car will move in a larger-radius curve and leave the roadway. Let's now consider banked curves, where the slope of the road helps in negotiating the curve. The greater the angle of the curve, the faster one can take the curve. It is common for race tracks for...
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Perpendicular-Axis Theorem01:16

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The perpendicular-axis theorem states that the moment of inertia of a planar object about an axis perpendicular to its plane is equal to the sum of the moments of inertia about two mutually perpendicular concurrent axes lying in the plane of the body.
Consider a circular disc of mass M and radius R lying along an x-y plane. The origin lies at the center of the disc, and the z-axis is perpendicular to the disc's plane. All three axes coincide at the disc's center. The moment of inertia of this...
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Gauss's Law: Planar Symmetry01:27

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A planar symmetry of charge density is obtained when charges are uniformly spread over a large flat surface. In planar symmetry, all points in a plane parallel to the plane of charge are identical with respect to the charges. Suppose the plane of the charge distribution is the xy-plane, and the electric field at a space point P with coordinates (x, y, z) is to be determined. Since the charge density is the same at all (x, y) - coordinates in the z = 0 plane, by symmetry, the electric field at P...
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Related Experiment Video

Updated: Jun 29, 2025

Kinematic History of a Salient-recess Junction Explored through a Combined Approach of Field Data and Analog Sandbox Modeling
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Can classical mechanics sense conical intersection?

Sourav Karmakar1, Saumya Thakur1, Amber Jain1

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Excitation of slow vibrational modes is key to energy relaxation, a phenomenon linked to vibrational conical intersections (CI). Both quantum-classical and classical simulations reveal this fast energy transfer, confirming CI

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Area of Science:

  • Physical Chemistry
  • Chemical Physics
  • Quantum Dynamics

Background:

  • Conical intersections (CI) are known to facilitate rapid electronic energy transfer.
  • Previous work established the existence of vibrational conical intersections (CI) and their role in vibrational energy relaxation.

Purpose of the Study:

  • To investigate the mechanism of vibrational energy relaxation in a model system.
  • To explore the role of vibrational mode timescales in energy relaxation.
  • To analyze the system using mixed quantum-classical and classical methods.

Main Methods:

  • Utilized an isolated model Hamiltonian system with four vibrational modes (two fast, two slow).
  • Employed mixed quantum-classical surface hopping simulations.
  • Performed completely classical simulations.

Main Results:

  • Demonstrated that the excitation of slow vibrational modes is crucial for the energy relaxation mechanism.
  • Observed fast energy relaxation in both surface hopping and classical simulations.
  • Identified fast energy relaxation as a signature of conical intersection (CI) existence.

Conclusions:

  • Vibrational conical intersections significantly influence vibrational energy relaxation dynamics.
  • Slow vibrational modes play a critical role in facilitating rapid energy dissipation.
  • Classical and mixed quantum-classical simulations can capture signatures of conical intersections.