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Published on: May 10, 2012
Stepwise Dissipative Control of Multimodal Motion in a Silver(I) Catenate
Emad Elramadi1, Sohom Kundu1, Debabrata Mondal1
1Center of Micro and Nanochemistry and (Bio)Technology, School of Science and Technology, Organische Chemie I, University of Siegen, Adolf-Reichwein Str. 2, 57068, Siegen, Germany.
Abstract:
Stepwise dissipative control of two distinct motions, i.e., shuttling and sliding, is demonstrated in a single multicomponent device. When [2]rotaxane 1, which acts as a biped, and deck 2 were treated with AgBF4/PhCH2Br+NEt3 as chemical fuel, the transient catenate [Ag(1)]+ ⋅ [Ag3(2)]3+ was instantly generated showing multimodal motion and autonomous return to 1 and 2. In the dissipative process, catenate [Ag(1)]+ ⋅ [Ag3(2)]3+ cleanly transformed into the follow-up transient device (1) ⋅ [Ag3(2)]3+ exhibiting only sliding motion. Two interference-free dissipative cycles proved the resilience and robustness of the process.
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