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Updated: Jun 29, 2025

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Monovalent Cation Doping of CH3NH3PbI3 for Efficient Perovskite Solar Cells
Published on: March 19, 2017
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Instant p-doping and pore elimination of the spiro-OMeTAD hole-transport layer in perovskite solar cells
Zhipeng Fu1, Tian Hou1, Xin Wang1
1School of New Energy and Materials, Southwest Petroleum University, Chengdu, 610500, China.
Abstract:
An instant p-doping strategy employing 4-tert-butyl-2-chloropyridine and tert-butyl peroxybenzoate for the spiro-OMeTAD hole-transport layer (HTL) in perovskite solar cells (PSCs) is proposed to replace the conventional 4-tert-butylpyridine-doped HTL. The novel doping process eliminates the formation of pores in the HTL. Meanwhile, a 21.4% efficiency is achieved on the corresponding absolute methylammonium-free PSCs with significantly improved thermal and moisture stability.

