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Arsenic field test kits based on solid-phase fluorescence filter effect induced by silver nanoparticle formation.

Wenhui Yang1, Liqing Ye1, Yuke Wu2

  • 1College of Chemistry and Material Science, Sichuan Normal University, Chengdu, Sichuan 610068, China; Key Laboratory of Green Chemistry & Technology of MOE, College of Chemistry, Sichuan University, Chengdu, Sichuan 610064, China.

Journal of Hazardous Materials
|March 29, 2024
PubMed
Summary

A new paper-based fluorescence assay enables low-cost, sensitive, on-site detection of arsenic in groundwater. This portable method helps identify safe drinking water sources and map global arsenic contamination.

Keywords:
ArsenicOn-sitePortable deviceSilver nanoparticleSolid-phase fluorescence filter effect

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Area of Science:

  • Environmental Science
  • Analytical Chemistry
  • Materials Science

Background:

  • Arsenic contamination in groundwater poses a global health risk.
  • Accurate and accessible field detection methods are crucial for public safety.

Purpose of the Study:

  • To develop a cost-effective, highly sensitive, and portable assay for on-site arsenic detection in water.
  • To enable rapid identification of safe wells and aid in global arsenic mapping.

Main Methods:

  • A novel paper-based fluorescence assay utilizing the solid-phase fluorescence filter effect (SPFFE).
  • Generation of silver nanoparticles (AgNPs) induced by arsine (AsH3) interacting with carbon dots.
  • Integration with a smartphone and a portable sensing platform for field analysis.

Main Results:

  • Achieved a low arsenic detection limit of 0.36 μg/L.
  • Demonstrated high sensitivity due to efficient Ag+ reduction and AgNP properties.
  • Validated accuracy against mass spectrometry for surface and groundwater samples.

Conclusions:

  • The developed SPFFE-based assay offers excellent sensitivity, portability, and low cost for arsenic analysis.
  • This system holds significant potential for widespread on-site water quality monitoring.
  • Facilitates rapid assessment of groundwater safety and contributes to global arsenic contamination mapping.